In 1898 Thomson recommended Rutherford for a position at McGill University in Montreal, Canada. He was to replace Hugh Longbourne Callendar who held the chair of Macdonald Professor of physics and was coming to Cambridge. Rutherford was accepted, which meant that in 1900 he could marry Mary Georgina Newton (1876–1954) to whom he had become engaged before leaving New Zealand; they married at St Paul's Anglican Church, Papanui in Christchurch, they had one daughter, Eileen Mary (1901–1930), who married Ralph Fowler. In 1901 he gained a DSc from the University of New Zealand. In 1907 Rutherford returned to Britain to take the chair of physics at the Victoria University of Manchester.Later years and honours:He was knighted in 1914. During World War I, he worked on a top secret project to solve the practical problems of submarine detection by sonar. In 1916 he was awarded the Hector Memorial Medal. In 1919 he returned to the Cavendish succeeding J. J. Thomson as the Cavendish professor and Director. Under him, Nobel Prizes were awarded to James Chadwick for discovering the neutron (in 1932), John Cockcroft and Ernest Walton for an experiment which was to be known as splitting the atom using a particle accelerator, and Edward Appleton for demonstrating the existence of the ionosphere. In 1925, Rutherford pushed calls to the Government of New Zealand to support education and research, which led to the formation of the Department of Scientific and Industrial Research (DSIR) in the following year. Between 1925 and 1930 he served as President of the Royal Society, and later as president of the Academic Assistance Council which helped almost 1,000 university refugees from Germany. He was appointed to the Order of Merit in the 1925 New Year Honours and raised to the peerage as Baron Rutherford of Nelson, of Cambridge in the County of Cambridge in 1931, a title that became extinct upon his unexpected death in 1937. In 1933, Rutherford was one of the two inaugural recipients of the T. K. Sidey Medal, set up by the Royal Society of New Zealand as an award for outstanding scientific research.
For some time before his death, Rutherford had a small hernia, which he had neglected to have fixed, and it became strangulated, causing him to be violently ill. Despite an emergency operation in London, he died four days afterwards of what physicians termed "intestinal paralysis", at Cambridge. After cremation at Golders Green Crematorium, he was given the high honour of burial in Westminster Abbey, near Isaac Newton and other illustrious British scientists.Scientific research:At Cambridge, Rutherford started to work with J. J. Thomson on the conductive effects of X-rays on gases, work which led to the discovery of the electron which Thomson presented to the world in 1897. Hearing of Becquerel's experience with uranium, Rutherford started to explore its radioactivity, discovering two types that differed from X-rays in their penetrating power. Continuing his research in Canada, he coined the terms alpha ray and beta ray in 1899 to describe the two distinct types of radiation. He then discovered that thorium gave off a gas which produced an emanation which was itself radioactive and would coat other substances. He found that a sample of this radioactive material of any size invariably took the same amount of time for half the sample to decay – its "half-life" (11½ minutes in this case).
From 1900 to 1903, he was joined at McGill by the young chemist Frederick Soddy (Nobel Prize in Chemistry, 1921) for whom he set the problem of identifying the thorium emanations. Once he had eliminated all the normal chemical reactions, Soddy suggested that it must be one of the inert gases, which they named thoron (later found to be an isotope of radon). They also found another type of thorium they called Thorium X, and kept on finding traces of helium. They also worked with samples of "Uranium X" from William Crookes and radium from Marie Curie.
In 1902, they produced a "Theory of Atomic Disintegration" to account for all their experiments. Up till then atoms were assumed to be the indestructable basis of all matter and although Curie had suggested that radioactivity was an atomic phenomenon, the idea of the atoms of radioactive substances breaking up was a radically new idea. Rutherford and Soddy demonstrated that radioactivity involved the spontaneous disintegration of atoms into other types of atoms (one element spontaneously being changed to another). The Nobel Prize in Chemistry 1908 was awarded to Ernest Rutherford "for his investigations into the disintegration of the elements, and the chemistry of radioactive substances".
In 1903, Rutherford considered a type of radiation discovered (but not named) by French chemist Paul Villard in 1900, as an emission from radium, and realised that this observation must represent something different from his own alpha and beta rays, due to its very much greater penetrating power. Rutherford therefore gave this third type of radiation the name of gamma ray. All three of Rutherford's terms are in standard use today – other types of radioactive decay have since been discovered, but Rutherford's three types are among the most common.
In Manchester, he continued to work with alpha radiation. In conjunction with Hans Geiger, he developed zinc sulfide scintillation screens and ionisation chambers to count alphas. By dividing the total charge they produced by the number counted, Rutherford decided that the charge on the alpha was two. In late 1907, Ernest Rutherford and Thomas Royds allowed alphas to penetrate a very thin window into an evacuated tube. As they sparked the tube into discharge, the spectrum obtained from it changed, as the alphas accumulated in the tube. Eventually, the clear spectrum of helium gas appeared, proving that alphas were at least ionised helium atoms, and probably helium nuclei.Gold foil experiment:Rutherford performed his most famous work after receiving the Nobel prize in 1908. Along with Hans Geiger and Ernest Marsden in 1909, he carried out the Geiger–Marsden experiment, which demonstrated the nuclear nature of atoms by deflecting alpha particles passing through a thin gold foil. Rutherford was inspired to ask Geiger and Marsden in this experiment to look for alpha particles with very high deflection angles, of a type not expected from any theory of matter at that time. Such deflections, though rare, were found, and proved to be a smooth but high-order function of the deflection angle. It was Rutherford's interpretation of this data that led him to formulate the Rutherford model of the atom in 1911 – that a very small charged nucleus, containing much of the atom's mass, was orbited by low-mass electrons.
Before leaving Manchester in 1919 to take over the Cavendish laboratory in Cambridge, Rutherford became, in 1919, the first person to deliberately transmute one element into another. In this experiment, he had discovered peculiar radiations when alphas were projected into air, and narrowed the effect down to the nitrogen, not the oxygen in the air. Using pure nitrogen, Rutherford used alpha radiation to convert nitrogen into oxygen through the nuclear reaction 14N + α → 17O + proton. In the products of this reaction Rutherford simply identified hydrogen nuclei, by their similarity to the particle radiation from earlier experiments in which he had bombarded hydrogen gas with alpha particles to knock hydrogen nuclei out of hydrogen atoms. This result showed Rutherford that hydrogen nuclei were a part of nitrogen nuclei (and by inference, probably other nuclei as well). Such a construction had been suspected for many years on the basis of atomic weights which were whole numbers of that of hydrogen; see Prout's hypothesis. Hydrogen was known to be the lightest element, and its nuclei presumably the lightest nuclei. Now, because of all these considerations, Rutherford decided that a hydrogen nucleus was possibly a fundamental building block of all nuclei, and also possibly a new fundamental particle as well, since nothing was known from the nucleus that was lighter. Thus, confirming and extending the work of Wilhelm Wien who in 1898 discovered the proton in streams of ionized gas, Rutherford postulated the hydrogen nucleus to be a new particle in 1920, which he dubbed the proton.
In 1921, while working with Niels Bohr (who postulated that electrons moved in specific orbits), Rutherford theorized about the existence of neutrons, (which he had christened in his 1920 Bakerian Lecture), which could somehow compensate for the repelling effect of the positive charges of protons by causing an attractive nuclear force and thus keep the nuclei from flying apart from the repulsion between protons. The only alternative to neutrons was the existence of "nuclear electrons" which would counteract some of the proton charges in the nucleus, since by then it was known that nuclei had about twice the mass that could be accounted for if they were simply assembled from hydrogen nuclei (protons). But how these nuclear electrons could be trapped in the nucleus, was a mystery.
Rutherford's theory of neutrons was proved in 1932 by his associate James Chadwick, who recognized neutrons immediately when they were produced by other scientists and later himself, in bombarding beryllium with alpha particles. In 1935, Chadwick was awarded the Nobel Prize in Physics for this discovery. LegacyNuclear physics:Rutherford's research, and work done under him as laboratory director, established the nuclear structure of the atom and the essential nature of radioactive decay as a nuclear process. Rutherford's team, using natural alpha particles, demonstrated induced nuclear transmutation, and later, using protons from an accelerator, demonstrated artificially-induced nuclear reactions and transmutation. He is known as the father of nuclear physics. Rutherford died too early to see Leó Szilárd's idea of controlled nuclear chain reactions come into being. However, a speech of Rutherford's about his artificially-induced transmutation in lithium, printed in 12 September 1933 London paper The Times, was reported by Szilárd to have been his inspiration for thinking of the possibility of a controlled energy-producing nuclear chain reaction. Szilard had this idea while walking in London, on the same day.
Rutherford's speech touched on the 1932 work of his students John Cockcroft and Ernest Walton in "splitting" lithium into alpha particles by bombardment with protons from a particle accelerator they had constructed. Rutherford realized that the energy released from the split lithium atoms was enormous, but he also realized that the energy needed for the accelerator, and its essential inefficiency in splitting atoms in this fashion, made the project an impossibility as a practical source of energy (accelerator-induced fission of light elements remains too inefficient to be used in this way, even today). Rutherford's speech in part, read:
We might in these processes obtain very much more energy than the proton supplied, but on the average we could not expect to obtain energy in this way. It was a very poor and inefficient way of producing energy, and anyone who looked for a source of power in the transformation of the atoms was talking moonshine. But the subject was scientifically interesting because it gave insight into the atoms.